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No. 39: May-Jun 1985

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Forbidden Matter

When a hot mixture of aluminum and manganese, iron or chromium is squirted onto a spinning water-cooled copper wheel, the molten metal freezes into a thin, metallic ribbon. If it is cooled too fast, a metallic glass results; cooled too slowly, it forms normal metal crystals. But when conditions are just right, icosahedral crystals cluster together in nodules a few microns in size. These icosahedral crystals are not normal in the sense that they have five-fold symmetry. In fact, to a crystallographer, these crystals are the equivalent to ESP in psychology.

All the rules of crystallography insist that icosahedral crystals should not exist. One scientist reacted in this way:

"All my training has been with the assumption that crystals are periodic. Now, almost everything has to be reexamined."

Actually, the icosahedral crystals are "quasi-periodic"; that is, they are completely regular only over small distances. Nevertheless, there are hints that these materials that should not exist have remarkable structural and electronic properties.

(Peterson, Ivars; "The Fivefold Way for Crystals," Science News, 127:188, 1985.)

Two-dimensionsal quasiperiodic geometry (Penrose tiling)
Two-dimensionsal quasiperiodic geometry (Penrose tiling) with five-fold symmetry formerly thought to be impossible in nature.

Tricontahedron with 30 faces
The tricontahedron with 30 faces is the basis of three-dimensional quasiperiodic structures with five-fold symmetry.

From Science Frontiers #39, MAY-JUN 1985. © 1985-2000 William R. Corliss

Science Frontiers Sourcebook Project Reviewed in:

Quotes

  • "Before opening the book, I set certain standards that a volume which treads into dangerous grounds grounds like this must meet. The author scrupulously met, or even exceeded those standards. Each phenomenon is exhaustively documented, with references to scientific journals [..] and extensive quotations" -- "Book Review: The moon and planets: a catalog of astronomical anomalies", The Sourcebook Project, 1985., Corliss, W. R., Journal of the Royal Astronomical Society of Canada>, Vol. 81, no. 1 (1987), p. 24., 02/1987